You sound fairly new to IT, in which case there are a couple of perennial ways in that you could consider:
Look for software testing jobs. For somebody with aptitude and enthusiasm, these can lead on to other things. Don't let recruitment agents discourage you if you go this route as somebody with not a lot of experience. It can be done.
Do something with Excel. If you do this right then it could pay relatively well quite quickly, particularly if you can learn VBA. Not very exciting, perhaps, although it's a start and it can lead on to other things.
There are two essential sites if you're looking for IT jobs in London:
http://www.jobserve.com for, um, jobs
http://www.itjobswatch.co.uk for salary ranges, number of open positions and their trends over time
If you would like a chat or a mock interview, let me know. I've interviewed a lot of people for IT jobs. The main thing in IT is not to bluff.